| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1402996 | Journal of Molecular Structure | 2013 | 5 Pages |
Abstract
⺠[MCl2(η2-N,N-dpksc)] (M = Zn, Cd or Hg; and dpksc = di-2-pyridylketone semicarbazone) were prepared from the direct reactions between MCl2 and dpksc in CH3CN. ⺠The amine protons are more sensitive to temperature variations compared to the amide proton. ⺠Reversible inter-conversion between [MCl2(η2-N,N-dpksc)] and its conjugate base was established. ⺠[MCl2(η2-N,N-dpksc)] and dpksc are not stable to redox transformations.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Spectroscopic, and electrochemical studies of [MCl2(η2-N,N-dpksc)] (M = Zn, Cd, Hg and dpksc = di-2-pyridylketone semicarbazone)](/preview/png/1402996.png "First Page Preview: Spectroscopic, and electrochemical studies of [MCl2(η2-N,N-dpksc)] (M = Zn, Cd, Hg and dpksc = di-2-pyridylketone semicarbazone)")
Authors
Mohammed Bakir, Covel McDermot, Toni Johnson,