Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1403249 | Journal of Molecular Structure | 2013 | 7 Pages |
A series of five-membered heterocyclic 1,2,3-triazole derivatives with different substituents in N1 position was synthesized. The heterocyclic moiety was connected through an ester function to a p-decyloxyphenyl or p-decyloxybiphenyl tails Polarized microscopy studies, X-ray scattering and differential scanning calorimetry (DSC) analysis revealed that the target compounds exhibit enantiotropic liquid crystalline properties. Their mesomorphic behavior is closely related to the nature of the substituent X present in N1 position of the heterocycle.
► Novel [1,2,3]-triazole based mesogenic derivatives were synthesized and characterized. ► The smectic A phase appeared to be the dominant phase in these structures. ► The incorporation of an ester function within the triazole unit could generate enough dipole which promotes the arrangement of molecules in smectic layer structures. ► The mesomorphic behavior is closely related to the nature of the substituent X present in N1 position of the heterocycle. ► The increase of the mesogenic length causes a decrease in the existence range of the smectic A mesophase in favor of a new nematic mesophase.