| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1404555 | Journal of Molecular Structure | 2006 | 4 Pages |
Abstract
A new para-sulphonatocalix[4]arene supramolecular packing architecture with triethylammonium ligands has been determined. The structure is based on a “stepped bilayer” formed by para-sulphonatocalixarenes in which triethylammonium cations are complexed in two different manners, with one cation included in the macrocyclic cage and the other situated externally in the hydrophobic interlayer environment. This architecture is quite different from those observed in the case of arginine, lysine or other alkylammonium complexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![A stepped bilayer packing motif for para-sulphonatocalix[4]arene: The solid-state structure of the para-sulphonatocalix[4]arene-triethylamine complex](/preview/png/1404555.png "First Page Preview: A stepped bilayer packing motif for para-sulphonatocalix[4]arene: The solid-state structure of the para-sulphonatocalix[4]arene-triethylamine complex")
Authors
Florent Perret, Stéphanie Guéret, Oksana Danylyuk, Kinga Suwinska, Anthony W. Coleman,