| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1404558 | Journal of Molecular Structure | 2006 | 6 Pages |
Abstract
K2[MoO2(O2CCOPh2)2] · 2H2O (1) and K2[WO2(O2CCOPh2) · 1.5H2O (2) have been synthesized by the reactions of (NH4)2MS4 (M = Mo, W) and benzilate (hydroxydiphenylacetate) in water-alcohol medium at room temperature. The two complexes are characterized by elemental analysis, infrared spectra, 1H NMR and TGA/DTA. When irradiated to UV light, both complexes exhibit photochromism in the solid state and their UV-induced products have been characterized by X-ray photoelectronic spectra and electron paramagnetic resonance spectra.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Synthesis, structural determination and photochromism characterization of two complexes with [MO2(O2CCOPh2)2]2â cores [MÂ =Â Mo or W]](/preview/png/1404558.png "First Page Preview: Synthesis, structural determination and photochromism characterization of two complexes with [MO2(O2CCOPh2)2]2â cores [MÂ =Â Mo or W]")
Authors
Li-Feng Cui, Dong-Mei Li, Jun-Feng Wu, Xiao-Bing Cui, Tie-Gang Wang, Ji-Qing Xu,