Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1404576 | Journal of Molecular Structure | 2006 | 5 Pages |
Abstract
A novel copper(II) complex containing the peptide phe-leu has been prepared and characterized. The crystal structure of [Cu(phe-leu)] (1) was determined by X-ray diffraction. The presence of carboxylate and amido bridges allows the formation of an extended 2D arrangement. This structure is similar to those found in [Cu(gly-val)] · 1/2H2O (2), [Cu(val-gly)] (3), [Cu(val-phe)] (4), and [Cu(phe-phe)] (5). The magnetic properties of compounds 1–5 were studied and analyzed comparatively. The experimental data show that the magnetic interactions are mainly transmitted through μ2-COO− bridges, being ferromagnetic for 1 and 3, and antiferromagnetic for 2, 4 and 5.
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Authors
J. Sanchiz, C. Kremer, M.H. Torre, G. Facchin, E. Kremer, E.E. Castellano, J. Ellena,