Synthesis, crystal structure, thermal analysis, vibrational study dielectric behaviour and Hirshfeld surface analysis of [C6H10(NH3)2)]2 SnCl6 (Cl)2

•The octochlorostannate SnCl6 form infinite chains which are centered respectively on Sn1 and Sn2 polyhedral, the purity of this synthesis is confirmed by many analysis studies.•The thermal behavior of this compound is in agreement with the electrical properties of crystal.•The electrical study permit to attribute a simple RC equivalent circuit for the title compound.

A new organotin (IV), bis 1-2 diammonium cyclohexane octachlorotin dichloride, have been synthesized. The molecular structures of the complexes have been determined using single crystal X-ray diffraction analysis reveals that complexes crystallizes in orthorhombic space group P4/n with a = 13.014(3)Å, b = 13.014(3), c = 16.822(4)Å, V = 2849.0(11)Å3. The structure consists of three-dimensional tanks framework. They show further that the tin (IV) ion is octahedral surrounded by six atoms with six chloride ligands, tow [C6H10(NH3)2]2+ cations and tow isolated chloride ion Cl−.The new compound has been characterized by differential scanning calorimetric (DSC) technique, 13C MAS-NMR, FT-IR, RAMAN spectroscopic studies and dielectric properties are detected in the frequency interval of 209 Hz–5 MHz and in the temperature interval of 313–373 K, have been carried out in order to characterize the complexes, the Hirschfeld surface analysis have been performed to gain insight into the behavior of these weak interactions.