Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1405737 | Journal of Molecular Structure | 2012 | 6 Pages |
This work reports on the synthesis of novel unsymmetrically substituted magnesium phthalocyanine complexes containing one carboxyl group. The physicochemical behavior of these complexes were compared with those of their unmetallated and zinc counterparts. The MgPcs showed interesting absorption spectra with [8,15,22-Tris-(naphtho)-4,5-(3-carboxy-1,2-dioxyphenyl)phthalocyaninato]magnesium (II) showing a large split in the Q band whereas [8,15,22-Tris-(naphtho)-2-(carboxy) phthalocyaninato]magnesium(II) presented only a small splitting. The magnesium phthalocyanine derivatives displayed higher fluorescence quantum yields compared to unmetallated and zinc phthalocyanine counterparts. The latter gave admirable triplet and singlet oxygen quantum yields. These molecules can distinctly be employed in the field of photodynamic therapy in combination with fluorescence imaging.
► Monocarboxy MgPc complexes were synthesized. ► Their photophysical behaviour were compared to those of ZnPc and H2Pc Counterparts. ► The Q band absorption is split for MgPc and not for ZnPc derivatives. ► MgPc give lower triplet quantum yields.