Article ID Journal Published Year Pages File Type
1405744 Journal of Molecular Structure 2012 10 Pages PDF
Abstract
► Propellane: tricyclic compound with elongated conjoining bond common for three rings. ► Conformation of propellane molecule is imposed by the rigidity of the whole molecule. ► Boat conformation of cyclohexene ring is the most stable one for such propellanes. ► Tetrahydrofurane rings adopt the envelope conformation with a low inversion barrier. ► Low inversion barrier of tetrahydrofurane rings caused disorder in crystal structure.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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