| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1405797 | Journal of Molecular Structure | 2014 | 5 Pages |
•A pcu network based on dinuclear Ni(II) units has been hydrothermally synthesized.•Two Ni(II) ions are bridged by two carboxylate groups in the syn-anti mode.•The dominant ferromagnetic interactions exist between Ni(II) ions.
A pcu network based on the dinuclear Ni(II) units, [Ni2(hfipbb)2(1,3-bix)2]n (1) (H2hfipbb = 4,4′- (Hexafluoroisopropylidene)bis(benzoic Acid); 1,3-bix = 1,3-bis(imidazol-1-ylmethyl)benzene), has been hydrothermally synthesized and structurally characterized. Interestingly, the two Ni(II) cations are bridged by two carboxylate groups in the rarely-seen syn-anti mode. The magnetic data reveal the dominant ferromagnetic interactions between Ni(II) ions.
Graphical abstractA pcu network based on the dinuclear Ni(II) units has been hydrothermally synthesized and structurally characterized. Interestingly, the two Ni(II) cations are bridged by two carboxylate groups in the rarely-seen syn-anti mode. The magnetic data reveals the dominant ferromagnetic interactions between the Ni(II) ions.Figure optionsDownload full-size imageDownload as PowerPoint slide
