| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1405812 | Journal of Molecular Structure | 2012 | 6 Pages |
Three new coumarin derivatives, namely, 6-phenylazo-3-[3-(4-formylphenyl)prop-2-enoyl]-coumarin (2a), 6-phenylazo-8-methoxy-3-[3-(4-formylphenyl)prop-2-enoyl]-coumarin (2b), and 6-(4-methoxyphenyl)azo-3-[3-(4-formylphenyl)prop-2-enoyl]-coumarin (2c), were synthesized and characterized. The three compounds exhibited high fluorescence quantum yields, strong blue emissions under UV light excitation, and high thermal stabilities, as determined by thermogravimetric (TG) analysis. The excited-state geometry was optimized at the CIS level of theory, whereas the B3LYP level of theory was applied for the ground state. The absorption and emission spectra were calculated using the time-dependent density functional theory (TD-DFT) in combination with the polarized continuum model (PCM). Resonance frequency calculations were undertaken to study the infrared spectra of the three compounds. The calculated results are in very good agreement with the experimental data.
► Three novel ketocoumarins were synthesized and spectroscopically investigated. ► The three compounds possess excellent thermal stability. ► The three compounds exhibit high fluorescence quantum yield and bright blue emission. ► Quantum chemical calculations were utilized to support the experimental findings. ► They may be used as blue dopants in organic light-emitting diodes (OLEDs).
