| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1405931 | Journal of Molecular Structure | 2012 | 10 Pages |
Abstract
⺠The new piperidin-4-one adopts chair conformation with equatorial substituents. ⺠The N-benzylpiperidin-4-ones are also in the chair conformation with equatorial substituents. ⺠The highly crowded 3,5-dialkylcompounds also adopt similar stereochemistry of 3-alkyl analogs. ⺠The N-benzylation significantly changed the chemical shifts but no conformational changes. ⺠The N-benzylpiperidin-4-ones exist in the chair form in solid state as well, witnessed by XRD.
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Authors
Someshwar D. Dindulkar, Paramasivam Parthiban, Vedavati G. Puranik, Yeon Tae Jeong,