| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1405955 | Journal of Molecular Structure | 2013 | 6 Pages |
•Complex 1 and 2 are distinct structural characteristic: twofold interpenetrating diamondlike framework for 1 and a noncatenated structure based on infinite[Cu(SCN)]n chains for 2.•The symmetry matching of their secondary building unit (SBU) are of particular importance to control their degree of interpenetration.•Tetrakis(3-pyridyloxymethylene) methane (L) can be served as a good candidate for the construction of MOFs due to its specific tetrahedral configuration and flexible conformation.
Two new coordination polymers based on CuX (X = SCN, I) and L have been successfully prepared by solvothermal reactions: [Cu4I4L] (1) and [Cu4(SCN)4L] (2) (L = tetrakis(3-pyridyloxymethylene)methane), exhibiting a doubly-fold interpenetrating diamondlike framework for 1 and a noncatenated structure with infinite[Cu(SCN)]n chains for 2. Their structural analysis shows the symmetry matching of their secondary building unit (SBU) can effectively control their degree of interpenetration.
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