| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1406232 | Journal of Molecular Structure | 2011 | 5 Pages |
Abstract
New polymorphic modification of MgPc(H2O) was obtained and its single crystal structure determined. It crystallizes in non-centrosymmetric space group P21 of the monoclinic system. Mg atom exhibits 4 + 1 type environment, consisting of four N isoindole atoms and apical O atom of water molecule. Spectroscopic studies indicate that the crystals possess solid-state broad-band near-IR absorption. The origin of the band broadening along with the comparison with two already known modifications is discussed.
► New modification of aqua magnesium(II) phthalocyanine was obtained. ► The crystal structure of MgPc(H2O) was determined. ► The investigations were perfomed due to dual goals: (1) its similarity to chlorophyll and (2) its optical properies.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vasyl Kinzhybalo, Jan Janczak,