Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1406267 | Journal of Molecular Structure | 2010 | 6 Pages |
Abstract
Reaction of vinyl acetate (3), 2-propyne-1-ol (4) and styrene (5) as dipolarphiles with N-[4-nitrophenyl]-C-[2-furyl] nitrilimine which was generated in situ has been shown to afford 3-(furan-2-yl)-1-(4-nitrophenyl)-4,5-dihydro-1H-pyrazol-5-yl acetate (6), (3-(furan-2-yl)-1-(4-nitrophenyl)-1H-pyrazol-5-yl)methanol (8) and 3-(furan-2-yl)-1-(4-nitrophenyl)-5-phenyl-4,5-dihydro-1H-pyrazole (10). Reactivity and regiochemistry of these reactions were investigated using DFT-based reactivity indexes.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
M. Bakavoli, F. Moeinpour, A. Davoodnia, A. Morsali,