Article ID Journal Published Year Pages File Type
1406405 Journal of Molecular Structure 2009 5 Pages PDF
Abstract

The structures of the metallo-xanthate anions [Zn(S2COR)3]− (R = Et (1), Pri (2)), [Sn(S2COR)3]− (R = Et (3), Pri (4)), and [Bi(S2COPri)4]− (5) have been determined as their [Me4N]+ salts. The two zinc species differ in having either all S,S bonded ligands (1) or both S,S and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dimers (3), while 5 adopts a monomeric dodecahedral structure.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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