Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1406405 | Journal of Molecular Structure | 2009 | 5 Pages |
Abstract
The structures of the metallo-xanthate anions [Zn(S2COR)3]− (R = Et (1), Pri (2)), [Sn(S2COR)3]− (R = Et (3), Pri (4)), and [Bi(S2COPri)4]− (5) have been determined as their [Me4N]+ salts. The two zinc species differ in having either all S,S bonded ligands (1) or both S,S and S,O-ligation (2). The tin compounds are either monomeric (4) or weakly associated into dimers (3), while 5 adopts a monomeric dodecahedral structure.
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Authors
A. ur Rehman, S. Ali, G. Kociok-Köhn, K.C. Molloy,