| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1406443 | Journal of Molecular Structure | 2010 | 4 Pages |
Abstract
A complex of the composition [Ni2(Hpyco)2(epa)(EtOH)Cl3] (1) (Hpyco = pyridine-2-carbaldehyde oxime; Hepa = 3-(ethoxycarbonyl)picolinic acid) has been synthesized via solvothermal synthetic reaction, and fully characterized by X-ray single crystal diffraction, IR and elemental analysis. Crystal structure revealed that 1 contains carboxylic oxygen atom bridged and chloro bridged dinuclear core with each Ni(II) exhibiting pseudo-octahedral geometry. An ester was formed in situ by the reaction of solvent ethanol with one carboxylic group of pyridine-2,3-dicarboxylic acid. Low-temperature magnetic susceptibility measurement for the solid sample of 1 revealed the ferromagnetic NiII⋯NiII interactions.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lina Zheng, Suyun Zhang, Kai Li, Wenqian Chen, Yanmei Chen, Bin Xu, Bin Hu, Yahong Li, Wu Li,