| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1406448 | Journal of Molecular Structure | 2010 | 4 Pages |
Abstract
The intermediate of the reaction between cyclobutanone and diethylamine has been crystallized in situ in form of co-crystal with diethylamine and its structure has been determined by X-ray crystallography. The study made possible to have an insight in the mechanism of the reaction and reveals the potential of in situ cryo-crystallization technique as an additional tool for studying the mechanisms of chemical reactions. The related structure of co-crystal of diethylamine with adipic acid, which is a product of cyclohexanone oxidative cleavage, is also reported.
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Authors
Dmitry S. Yufit, Judith A.K. Howard,