| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1406472 | Journal of Molecular Structure | 2010 | 4 Pages |
Abstract
A new mixed ligand cationic-anionic nickel(II) complex, [NiL2][Ni(NCS)4(H2O)2] (1), where LÂ =Â 1,4-diazepane has been synthesized by reacting nickel perchlorate with 1,4-diazepane and ammonium thiocyanate in the 1:1:2Â M ratio. The complex has been characterized by elemental analysis, IR spectroscopy, TGA and single crystal X-ray diffraction studies. Structural studies reveal the presence of two independent mononuclear complex ions in 1 viz., a square planar [NiL2]2+ and an octahedral [Ni(NCS)4(H2O)2]2â which are held together by H-bonding to form a 3D supramolecular structure in the solid state.
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Authors
Saugata Sain, Rajat Saha, Guillaume Pilet, Debasis Bandyopadhyay,