Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1406909 | Journal of Molecular Structure | 2010 | 6 Pages |
Abstract
Two novel non-centrosymmetric coordination polymer, [Zn2(PIDC)(H2O)Cl]n (1) and {[Mn(HPIDC)H2O]·2H2O}n (2) have been synthesized through hydrothermal method and characterized by IR, elemental analysis and single-crystal X-ray diffraction. Complex 1 crystallized in a chiral space group P212121 has a 2D network structure. Complex 2 is a 3D open framework with 1D channel where 1D zigzag water chains are reside through hydrogen-bonding interactions and crystallized in a chiral space group Cc. Both 1 and 2 display a strong second harmonic generation (SHG) response.
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Authors
Li-Zhuang Chen, Yao Huang, Ren-Gen Xiong, Hong-Wen Hu,