Article ID Journal Published Year Pages File Type
1407084 Journal of Molecular Structure 2008 5 Pages PDF
Abstract
A novel one-dimensional Wells-Dawson-based compound H2(bbi)0.5[Ni(phen)(bbi)2]2[P2W18O62] (phen = 1,10′-phenanthroline, bbi = 1,1′-(1,4-butanediyl)bis(imidazole)), has been prepared under the hydrothermal conditions and structurally characterized by elemental analysis, cyclic voltammetry, IR and XPS spectra and single-crystal X-ray diffraction. The title compound exhibits an interesting wavelike chain constructed from Dawson type polyoxoanion and mixed rigid and flexible ligands decorated [Ni(phen)(bbi)2]2+ cationic complex. It represents the first example of polyoxometalate that built from the rigid and flexible ligands at the same time.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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