Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1407226 | Journal of Molecular Structure | 2008 | 6 Pages |
Abstract
Two novel 1D organic-inorganic hybrid materials based on phosphomolybdates clusters, [Cu(phen)(H2O)]3[(PO4)2Mo5O15]·5H2O (1), HNa[Cu(bpy)(H2O)]2[(PO4)2Mo5O15]·6H2O (2), (phen = 1,10-phenanthroline, bpy = 2,2â²-bipyridine) have been solvothermally synthesized and characterized by the elemental analyses, IR, TG analysis and EPR. The single crystal X-ray diffraction reveals that the compound 1 is built from a propeller-shaped chain constructed from {(PO4)2Mo5O15}6â clusters linked through {Cu(phen)(H2O)}2+ components as blades. Also the compound 2 is based on {(PO4)2Mo5O15}6â polyoxoanion, further connected by {Cu(bpy)(H2O)}2+ subunits. The chains are integrated via hydrogen bonding and Ï-Ï stacking interaction to form a 3D framework.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xiaoming Lu, Xiaojun Wang, Peizhou Li, Xiuhuan Pei, Chaohui Ye,