Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1407859 | Journal of Molecular Structure | 2006 | 6 Pages |
Abstract
Three new cobalt(II) complexes [Co(bbta)2(MeOH)2(NCS)2] (1), [Co(bbta)(DMF)2(NCS)2]n (2) and [Co(bbta)3(NCS)2]n (3) were synthesized in the different solvent systems using the flexible ligand 1,2-bis(benzotriazol-1-yl)ethane (bbta) and the anion ligand thiocyanate. The X-ray diffraction analysis shows that 1 is a mononuclear, while 2 and 3 form the different zigzag chain structures. A conformation analysis of the ligand molecule demonstrates that the diversity in the ligand conformations leads to a variation in structural motifs.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Junhui Zhou, Xungao Liu, Yumei Zhang, Baolong Li, Yong Zhang,