Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1407960 | Journal of Molecular Structure | 2006 | 5 Pages |
Abstract
A new charge transfer salt, [NBu4]6H[Fe(C5H5)2][PMo12O40]2, based on Fe(C5H5)2 (ferrocene) and Keggin-type anion [PMo12O40]3â was electrochemically synthesized and its structure was determined by single-crystal X-ray diffraction. Monoclinic, C2/c, M=4068.12, a=50.383(18)Â Ã
, b=14.113(5)Â Ã
, c=26.554(10)Â Ã
, β=115.318°, V=17068(11) Ã
3, Z=6, R1=0.0759, wR2=0.1744 (I>2Ï). The layers of the organic donor and inorganic acceptor in solid state are alternatively arranged in (001) plates and each [Fe(C5H5)2]+ is surrounded by four Keggin-type anions. There are weak interactions between organic and inorganic layers. ESR spectrum at 110Â K displays distinct ferrocenyl cation [Fe(C5H5)2]+ and Mo5+ signals, the anion [PMo12O40]3â is reduced by one electron. The CV properties of the complex were also discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Xuemei Liu, Ganglin Xue, Huaiming Hu, Quanchang Gao, Feng Fu, Jiwu Wang,