Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1407972 | Journal of Molecular Structure | 2006 | 6 Pages |
Abstract
The reactions between OVCl3 and a series of silanes have been investigated using matrix isolation infrared spectroscopy. Twin-jet co-deposition of the two reagents into argon matrices at 14 K followed by irradiation with light of λ>300 nm led to the growth of a number of new bands. These have been assigned to the appropriate silanol species formed by oxygen insertion into the Si-H bond, complexed to VCl3. The structures and vibrational frequencies of these complexes have been characterized by high-level theoretical calculations. These calculations also support the relative preference for the insertion reaction compared to other possible pathways.
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Authors
Nicola Goldberg, Bruce S. Ault,