| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1407989 | Journal of Molecular Structure | 2015 | 7 Pages |
Abstract
New square planar nickel(II) complexes, [Ni(L1)2] (1) and [Ni(L2)2] (2) with thiophene appended Schiff's base ligands have been synthesized and characterized. Geometries of the complexes have been confirmed by single crystal X-ray studies. Absorption and emission properties have been studied. The complexes show quasi-reversible NiII/NiIII oxidation couple along with irreversible NiII/NiI reduction. Electronic structure and spectral properties are well interpreted by DFT and TDDFT calculations.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Subhankar Kundu, Sujan Biswas, Apurba Sau Mondal, Puspendu Roy, Tapan Kumar Mondal,