| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1407997 | Journal of Molecular Structure | 2015 | 5 Pages |
•Mixed-ligand europium carboxylates with nitrogen- and phosphorus-containing neutral ligands were synthesize.•The compounds were studied by the luminescent and X-ray photoelectron spectroscopy methods.•The value of electro-dipole 5D0–7F4 transition rise with decrease of the electron density transfer from Eu to ligand.
Mixed-ligand europium carboxylates with nitrogen- and phosphorus-containing neutral ligands having polymer or island structure were studied by the luminescent and X-ray photoelectron spectroscopy methods. In similar groups of the compounds, the value of Stark splitting of the 7F1 – level decreased with decrease of the electron density transfer from europium ion to ligand (covalence of metal-ligand bond increases) and the relative intensity of electro-dipole 5D0 – 7F4 transition rised.
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