Article ID Journal Published Year Pages File Type
1408320 Journal of Molecular Structure 2015 5 Pages PDF
Abstract

•Two new Zn(II) compounds tuned by different carboxylate ligands.•They show strong luminescence at room temperature.•A rare hybrid [(H2O)3(DMA)2] pentamer was found.

Two new inorganic–organic hybrid compounds with different topological structures, namely [Zn2(btc)(datrz)]n (1) and [Zn2(btec)(Hdatrz)]n (2) (H3btc = 1,3,5-benzenetricarboxylic acid, H4btec = 1,2,4,5-benzenetetracarboxylic acid, Hdatrz = 3,5-diamino-1,2,4-triazole), have been hydrothermally synthesized by the reactions of Zn(II) salt with H3btc and Hdatrz or H4btec and Hdatrz. Single X-ray analysis reveals that compound 1 is a three-dimensional (3D) pillar-layer framework and can be described as a 4-nodal net with the schläfli symbol of {4.62}2{4.64.8}2{4.65}2{42.610.82.10}, and compound 2 is also a three-dimensional (3D) framework and can be simplified into a 4-nodal topological network the schläfli symbol of {3.42.5.62}2{32.42.52.64.74.8}{32.44.54.62.73}{42.62.7.8}. In these two compounds, the Hdatrz ligand displays distinct coordination modes. Moreover, the luminescent properties of these two compounds were also investigated in the solid state at room temperature.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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