Article ID Journal Published Year Pages File Type
1408354 Journal of Molecular Structure 2015 5 Pages PDF
Abstract

•Ru(II) and Sn(IV)-porphyrins were synthesized.•2D DOSY NMR spectra for title compounds were studied.•The association constants were calculated.

Synthesis and NMR studies of Ru(II) and Sn(IV) tetraphenylporphyrins supramolecular complexes were carried out. The diffusion coefficients of the complexes, porphyrinates, and solvents were determined by DOSY NMR spectroscopy. By the method of spectrophotometric titration a binding ability of Ru(II) tetraphenylporphyrin towards 4-(imidazol-1-yl)-phenol was investigated, stability constant of resulting complexes and concentration intervals of their existence were defined.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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