| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1408558 | Journal of Molecular Structure | 2006 | 4 Pages |
Abstract
The rotational spectrum of bromoacetyl chloride, BrCH2COCl, has been assigned using a pulsed molecular beam Fourier transform microwave spectrometer. It has been possible to determine the rotational and quartic centrifugal distortion constants of the energetically favoured conformer (anti-periplanar) as well as the complete bromine and chlorine quadrupole coupling tensors including their off diagonal elements for the following isotopomers: 79BrCH2CO35Cl, 81BrCH2CO35Cl, 79BrCH2CO37Cl, and 81BrCH2CO37Cl. Experimental results are supported by quantum chemical calculations.
Related Topics
Physical Sciences and Engineering
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Authors
I. Merke, N. Vaeck, D. Petitprez, G. Wlodarczak,