Article ID Journal Published Year Pages File Type
1408956 Journal of Molecular Structure 2012 7 Pages PDF
Abstract
► Tetra-nuclear oxo- and chloroacetato-bridged iron(III) complex, from [Fe3O]+7 core. ► The tetra-nuclear entity consists of a [Fe4(μ3-O)2]8+ “bent-butterfly” unit. ► X-ray crystallography displays C2 axis perpendicular to the central Fe2O2 rhomboid. ► Four iron(III) centers exhibits strong antiferromagnetic exchange interactions. ► FeIII atoms on body/body site suffers frustration in the spin alignment with Jbb = 0.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, , , , ,