Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1409354 | Journal of Molecular Structure | 2014 | 5 Pages |
Abstract
Six new dinuclear Fe(III)/Cr(III)/Mn(III) complexes have been involved tetradentate (N2O2) Schiff bases (salenH2) and (salophenH2) with 2,4-bis(4-hydroxyphenylimino-4â²-formylphenoxy)-6-methoxy-1,3,5-triazine have been synthesized. The complexes were characterized as high-spin (SÂ =Â 5/2) distorted trigonal bipyramidal salen/salophenFe(III) bridged, distorted trigonal bipyramidal (SÂ =Â 3/2) salen/salophenCr(III) and high-spin distorted trigonal bipyramidal (SÂ =Â 2) salen/salophenMn(III) by OHâ groups. The structures of ligand and complexes were identified by using elemental analysis, thermal analysis, magnetic susceptibility, LC-MS, ICP-AES, 1H NMR and FT-IR spectral data.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Åeyma Ãelikbilek, Ziya Erdem Koç,