Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1409507 | Journal of Molecular Structure | 2011 | 5 Pages |
Abstract
The reaction of Cu(OH)2 (in situ synthesized from CuCl2·2H2O and NaOH), bpp and H2ox gave rise to a novel Cu(II) coordination polymer under ultrasonic irradiation at ambient temperature, namely [Cu(bpp)(ox)(H2O)·5H2O]n (1) (bpp = 1,3-bis(4-pyridyl)propane, H2ox = oxalic acid). In the complex 1, Cu(II) cations are bridged by bpp ligands to form a one-dimensional (1D) infinite wave-like polymeric chain. The coordinated ox2− anions and water molecules interact with each other by six different hydrogen-bonding motifs and extend the 1D polymeric chain into a two-dimensional (2D) bilayer pattern. Of further interest, one 1D T4(0)A(0) water tape consisting of alternate cyclic water tetramers resides in the channel structure of 1.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hong-Bo Xiong, Di Sun, Geng-Geng Luo, Rong-Bin Huang, Jing-Cao Dai,