| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1409599 | Journal of Molecular Structure | 2012 | 10 Pages |
Abstract
⺠Dioxygen oxidize some spirooctan-4-ones in DMSO (DMF)/NaOH stereoselectively. ⺠Hydroxylation do not change the ratio of stereoisomers obtained in cyclopropanation. ⺠DMSO was not oxidizing agent in alpha hydroxylation process. ⺠Sodium borohydride reduces some α-hydroxyketones to dioles stereoselectively. ⺠Three symmetry unique molecules in the crystal structure of α-hydroxyketone 2a1.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Stereochemistry of hydroxylation of some chiral spiro-[2,5]octan-4-ones](/preview/png/1409599.png "First Page Preview: Stereochemistry of hydroxylation of some chiral spiro-[2,5]octan-4-ones")
Authors
I.M. Gella, T.G. Drushlyak, N.S. Pivnenko, R.I. Zubatyuk, A.V. Turov, I.S. Konovalova, N.B. Novikova, O.V. Shishkin,