| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1409639 | Journal of Molecular Structure | 2011 | 6 Pages |
Abstract
A hybrid iodoargentate [(APHEN-H)2(Ag4I6)]n (1) (APHEN = 5-amino-1,10-phenanthroline) has been obtained by the routine synthetic reaction and structurally determined. In 1, a (Ag4I6)n2- chain was defined by edge-sharing of Ag4I6 units, and its quasi-three-dimensional hybrid structure was constructed from π–π interactions and CH⋯I hydrogen bonds. Experimental band gap of about 2.30 eV indicates its semiconductor nature. Strong luminescence can be detected in the title compound, which has been assigned by theoretical calculation with DFT method.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hao-Hong Li, Jun-Xiong Wu, Hai-Jun Dong, Yan-Ling Wu, Zhi-Rong Chen,