| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1409662 | Journal of Molecular Structure | 2012 | 4 Pages |
Abstract
Self-association of cumyl (CUH), tertiary butyl and 3-phenylmethyl hydroperoxides in various solvents and hetero-association of CUH with acetone and acetophenone in n-decane solutions were studied by FTIR spectroscopy. The obtained results were analyzed in combination with DFT data on linear and cyclic CUH self-associates. The analysis of the complexation enthalpies and entropies revealed compensation and cooperative effects, which were for the first time observed for H-bonding of hydroperoxides.
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Authors
A.B. Remizov, R.A. Skochilov,