Article ID Journal Published Year Pages File Type
1410075 Journal of Molecular Structure 2011 6 Pages PDF
Abstract
► Complexation of diallyldiphenylsilane with AgNO3 activated by tetraglyme. ► Ag-aromatic bonding promotes π-π stacking interaction. ► η2-Coordinated allyl groups are controlled by the σ(SiC)-π(CC) hyperconjugation.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
The first silver(I) nitrate π-complexes with unsaturated organosilicons: Synthesis and structural characterization of [Ag(DADPS)xNO3] (DADPS = diallyldiphenylsilane, x = 0.75; 1)
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