Article ID Journal Published Year Pages File Type
1410083 Journal of Molecular Structure 2011 6 Pages PDF
Abstract

Two new binuclear silver(I) complexes of 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine (PDT) and 3,5,6-tris(2-pyridyl)-1,2,4-triazine (TPT) ligands, [Ag2(PDT)2(NO3)2], 1, and [Ag2(TPT)2(NO3)2], 2, have been synthesized and characterized by elemental analysis, IR and 1H NMR spectroscopy, and also studied by thermal and electrochemical analysis as well as by X-ray crystallography. The individual dinuclear complexes in 1 are extended into a one-dimensional layered structure by weak Ag···CPDT (η3) interactions. The interesting features of the Ag(I) complexes are the different coordination modes of the ligands. The supramolecular features in these complexes are controlled by weak directional intra and intermolecular interactions.

► Two new binuclear silver(I) complexes based on of PDT and TPT ligands. ► The compounds characterized by spectroscopy technical and X-ray crystallography. ► The interesting features of compounds are different coordination modes of the ligands. ► Supramolecular features in these complexes are controlled by weak interactions.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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