Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410149 | Journal of Molecular Structure | 2010 | 9 Pages |
Abstract
A trinuclear nickel complex {[Ni3(HAmTrz)6·6H2O]·2H2O·6NO3]}n1 has been synthesized under hydrothermal condition and characterized by single-crystal X-ray crystallography, elemental analysis, IR, and TG/DTA. Nitrate anions of the crystal lattice are found to play an important role in the molecular self-assembly of [Ni3(HAmTrz)6.6H2O]6+ cationic building block into an overall three-dimensional network of 1 involving variety of homomeric R84(36) and heteromeric R22(8), R44(20), R88(41) supramolecular synthons. Furthermore, the material exhibits magnetic interaction of the Ni(II) centers existing in the whole trimeric building block.
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Organic Chemistry
Authors
Kafeel Ahmad Siddiqui, Gopal K. Mehrotra, J. Mrozinski, R.J. Butcher,