| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1410327 | Journal of Molecular Structure | 2009 | 5 Pages |
Abstract
A novel Re(IV) complex containing catechol as ligand has been prepared and characterized. The crystal structure of (HNEt3)(NBu4)[ReCl4(cat)]·H2cat was determined. The rhenium ion presents a distorted octahedral geometry, being bonded to a bidentate catecholate group and four chloride anions. The magnetic properties of the complex were studied, a /2D/ (the energy gap between ±3/2 and ±1/2 Kramers doublets) value of 190(10) cm−1. This is the largest /2D/ value reported for Re(IV) up to now.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
A. Cuevas, L. Geis, V. Pintos, R. Chiozzone, J. Sanchíz, M. Hummert, H. Schumann, C. Kremer,