| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1410341 | Journal of Molecular Structure | 2009 | 6 Pages |
Abstract
Bis(fluoroisatinato)mercury(II) was synthesised from the reaction between 5-fluoroisatin (HFI) and mercury(II) acetate in methanol. Mercury(II) coordination with nitrogen atom of 5-fluoroisatin molecule was observed using the FT-IR and NMR spectra of the product. Quantum chemistry calculations for 5-fluoroisatin (HFI) and bis(fluoroisatinato)mercury(II) (Hg(FI)2) were carried out. Vibrational analysis calculation at the RHF/LanL2DZ and B3LYP/LanL2DZ level was compared to the experimental solid-state data. UV-visible analyses were also studied.
Keywords
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Fatma Kandemirli, Baybars Köksoy, Taner Arslan, Seda Sagdınc, Halil Berber,