| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1410471 | Journal of Molecular Structure | 2009 | 5 Pages |
Abstract
A new cyanide-bridged heterobimetallic assembly based on octacyanotungstate(V) as building block, {[CuII(L)]3[WV(CN)8]2}·[CuII(L)·2H2O]·(ClO4)2·4H2O 1 (L = 3,10-dipropyl-1,3,5,8,10,12-hexaazacyclotetradecane), has been prepared and characterized. X-ray single-crystal analysis reveals that 1 displays a two-dimensional structure with corrugated sheets, in which the 12-membered rings are the basic building units. Magnetic studies reveal that 1 displays a ferromagnetic interaction between CuII and WV through cyano bridges.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ai-Hua Yuan, Wen-Yan Liu, Hu. Zhou, Ying-Ying Chen, Xiao-Ping Shen,