Article ID Journal Published Year Pages File Type
1410513 Journal of Molecular Structure 2009 7 Pages PDF
Abstract

Cross-linking of nitrosobenzenes to heterodimers (azodioxides) when they are not sterically crowded with large groups in ortho-position was studied by NMR and FT-IR spectroscopy, X-ray crystallography as well as by cryogenic photolysis. It was found for the first time that cross-linked dimers (heterodimers) exist both in solution and in solid state and that they appear in the crystal together with homodimers. The system is used as a model for studying organic solid solution formation. The role of molecular packing in formation of a weak chemical bond is also discussed.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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