Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410513 | Journal of Molecular Structure | 2009 | 7 Pages |
Abstract
Cross-linking of nitrosobenzenes to heterodimers (azodioxides) when they are not sterically crowded with large groups in ortho-position was studied by NMR and FT-IR spectroscopy, X-ray crystallography as well as by cryogenic photolysis. It was found for the first time that cross-linked dimers (heterodimers) exist both in solution and in solid state and that they appear in the crystal together with homodimers. The system is used as a model for studying organic solid solution formation. The role of molecular packing in formation of a weak chemical bond is also discussed.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ivan Halasz, Ivana Biljan, Predrag Novak, Ernest Meštrović, Janez Plavec, Gregor Mali, Vilko Smrečki, Hrvoj Vančik,