Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410805 | Journal of Molecular Structure | 2010 | 5 Pages |
Abstract
The solvent effect on the reactions of 3,5-di-O-p-toluoyl-d-2-deoxyribosyl chloride with alcohols has been studied with the help of density functional theory (DFT) method using the polarized continuum model (PCM). Moreover, the calculation allows a discussion of the solvent effect on the ratio of α- to β-anomer to compare with the experimental result. The results obtained by the present calculations are in excellent agreement with the experimental findings.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
QiaoCui Shi, Rong Sun, XiangWei Cheng,