Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410860 | Journal of Molecular Structure | 2007 | 5 Pages |
Abstract
19F and 199Hg high-resolution solution NMR spectra were acquired for cyclic trimeric perfluoro-ortho-phenylenemercury. Even with the high superconducting magnetic fields currently available, the 19F spectrum was not interpretable with a simple first-order analysis. Spectroscopic parameters for chemical shift and scalar coupling interactions in the NMR spectra were extracted from four- and five-spin simulations. Differential line widths in the 19F spectrum result from scalar coupling to the 199Hg.
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Authors
R.E. Taylor, François P. Gabbaï,