Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410863 | Journal of Molecular Structure | 2007 | 8 Pages |
Abstract
Two donor-π-acceptor (D-π-A) type 2,2′: 6′,2″-terpyridyl-based organic heterocyclic molecules have been efficiently synthesized via solvent-free Wittig reactions in good yields. One crystal structure of them was determined by single crystal X-ray diffraction determination. The two compounds exhibit sensitive single-photon-excited fluorescence (SPEF) emission with high fluorescence quantum yields and long lifetimes. The two-photon-excited fluorescence (TPEF), two-photon absorption (TPA) cross-sections and two-photon initiation polymerization (TPIP) microfabrication experiments have been investigated. Experimental results confirm that they are effective organic two-photon photopolymerization initiators.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Zhang-Jun Hu, Jia-Xiang Yang, Yu-Peng Tian, Hong-Ping Zhou, Xu-Tang Tao, Gui-Bao Xu, Wen-Tao Yu, Xiao-Qiang Yu, Min-Hua Jiang,