Article ID Journal Published Year Pages File Type
1410929 Journal of Molecular Structure 2010 4 Pages PDF
Abstract

A feasibility study has been undertaken to assess the suitability of a commercially available SERS substrate for monitoring of self-assembling deposition process. Monolayer self-assembly of 4-mercaptobenzoic acid on SERS active substrate Klarite™ from absolute and acidified ethanol was studied and compared with deposition on SPR substrate from absolute ethanol. Changes in integral intensity of the phenyl bands at 1587 and 1076 cm−1 and ethanol band at 1451 cm−1 allow to follow structural changes in the monolayer. Stability of the monolayer assembled from acidified ethanol in contrast to the pure ethanol was demonstrated.

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Physical Sciences and Engineering Chemistry Organic Chemistry
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