Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1410981 | Journal of Molecular Structure | 2007 | 5 Pages |
Abstract
A novel supramolecular mixed ligand complex of formula [Co(Phmal)(Him)4] (Phmal = phenylmalonate, Him = imidazole) has been synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), UV-Vis spectra. X-ray crystallographic studies of the complex reveal that the cobalt atom exhibits a distorted octahedral geometry being coordinated by four nitrogen atoms of Him ligands, two oxygen atoms from the phenylmalonate ligand. The intramolecular C-Hâ¯Ï interaction exists in the title complex. The three dimensional supramolecular network is constructed from the strong intermolecular N-Hâ¯O hydrogen bonds.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kou-Lin Zhang, Hai-Wei Kuai, Wen-Long Liu, Guo-Wang Diao,