| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1411684 | Journal of Molecular Structure | 2008 | 9 Pages |
Abstract
A complete study of the conformational behavior of cyclopentadecaphane by DNMR and theoretical methods demonstrates that: (a) the macrocycle adopts syn-orientation of indolizine fragments; (b) internal rotation around the bonds between indolizine and quinoxaline moieties produces two strictly different structures in solution: in dominant non-symmetrical form (ca. 67%) the halves of the macrocycle are not equivalent while in the minor symmetrical form (ca. 33%) they can be superimposed by rotation.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Alsu Balandina, Vakhid Mamedov, Shamil Latypov,