Article ID Journal Published Year Pages File Type
1411869 Journal of Molecular Structure 2007 4 Pages PDF
Abstract
We evaluate the enhancement factor of the effective mass, m∗/m, for polarons in a crystal composed of either the E ⊗ e or the T ⊗ t Jahn-Teller (JT) centers in the strong-coupling region. A much larger m∗/m is found in the T ⊗ t JT polarons than that in the E ⊗ e ones. This difference originates from the absence/presence of rotational symmetry in the pseudospin space representing the degeneracy of orbitals at each JT center.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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