| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1411903 | Journal of Molecular Structure | 2007 | 7 Pages |
Abstract
IR spectroscopy and ab initio calculations have been applied to the title compounds. Bicyclic acetals were found to exist as mixture of chair and twist-boat conformations, a parent epoxide being in ternary equilibrium. X-ray data on 4-methyl (exo) derivative display a twist-boat form.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
![Conformational isomerism in 3,5,8-trioxabicyclo[5.1.0]octane and its diastereomeric 4-methyl derivatives. A combined IR, X-ray and ab initio study](/preview/png/1411903.png "First Page Preview: Conformational isomerism in 3,5,8-trioxabicyclo[5.1.0]octane and its diastereomeric 4-methyl derivatives. A combined IR, X-ray and ab initio study")
Authors
A.E. Klimovitskii, E.E. Zvereva, G.A. Chmutova, A.B. Dobrynin, V.Yu. Fedorenko, Yu.G. Shtyrlin, I.A. Litvinov, T.V. Bulygina, E.N. Klimovitskii,